Q.

The reaction: A(g)2B(g)+C(g) is a first order reaction w.r.t.  A, with rate constant 1.386×104 sec-1 . If initially 0.1 mole/litre of A was taken and the reaction is occurring at constant pressure and temperature then the concentration of A after 5000 sec will b

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a

0.05 mole/litre

b

0.1 mole/litre

c

none of these

d

0.025 mole/litre

answer is B.

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Detailed Solution

for the reaction :

A(g)2B(g)+C(g)

1.386×104×5000=ln0.10.1x

x=0.12

nTotal =0.1+0.1=0.2

 At constant P,T;Vn

 New vol =2L

[A]new =0.14=0.025M

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