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Q.

The reaction: ArN2ClCu/HClArCl+N2 is known as :

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a

Sandmeyers reaction

b

Finkelstein reaction

c

Balz Schiemann reaction

d

Gattermann reaction

answer is C.

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Detailed Solution

ArN2+Cl  Cu/HCl  ArCl+N2ArN2+Cl  Cu/HBr  ArBr+N2ArN2+Cl  Cu/kCN  ArCN+N2

Copper powder and HX(or) KCN when heated with Benzene diazonium chloride gives  C6H5XorC6H5CN. This reaction is Gattermann’s reaction.

Note:– If Cu2Cl2/HCl,    Cu2Br2/HBr,  Cu2CN2/KCN  are used the reaction is Sandmeyer reaction where the reactants and product being the same.

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