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Q.

The reaction CH32O(g)CH4(g)+H2(g)+CO(g)follows first-order kinetics. The reaction is studied at constant volume with p0 as the initial pressure of CH32O. If p is the pressure at time t, then a linear plot will be observed between

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a

lnp/p0 versus t

b

lnpp0/p0 versus t

c

ln2pp0/p0 versus t

d

ln3pp0/2p0 versus t

answer is D.

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Detailed Solution

For a gaseous reaction at constant volume the rate constant is lnΔvg+1p0p/Δvgp0 versus t is a straight line for the first-order kinetics. In the present case, Δvg=2. Hence the plot of ln3p0p/2p0 versus twill a straight line

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