Q.

The reaction NH4CN(s)+32O2(g)N2(g)+CO2(g)+H2O(l) was carried out in a bomb calorimeter. The heat released was 743 kJ mol1. The value of ΔH300K for this reaction would be 

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a

740.5 kJ mol1

b

741.75 kJ mol1

c

743.0 kJ mol1

d

744.25 kJ mol1

answer is B.

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Detailed Solution

We have

 ΔH=ΔU+ΔvgRT=743+(1/2)8.314×103(300) kJ mol1 =741.75 kJ mol1

Hence, option B is correct.

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