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Q.

The reagent used for converting acetylene to oxalic acid is

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a

${HgSO}_{4} / aq H_{2} {SO}_{4}$

b

${HgSO}_{4} / {CH}_{3} COOH$

c

${KMnO}_{4} / KOH, 25 ° C$

d

${CrO}_{3} / H_{2} {SO}_{4}$

answer is C.

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Detailed Solution

Acetylene is $H - C \equiv C - H$

Oxalic acid is

Question Image

$C_{2} H_{2} \overset{{KMnO}_{4} / KOH, 25 ° C}{\to} (COOH)_{2}$

This is Baeyer’s test for unsaturation.

Hence, option (C) is correct.

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