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Q.

The relation between the keto contents x, y, z in percentage should be

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a

x > y > z

b

z > y > x

c

y > z > x

d

y > x > z

answer is A.

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Detailed Solution

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In case of x, enol form is stabilized by one -CH3 group(+Ieffect)

In case of y, enol form is stabilized by two -CH3 groups(more stable than in x)

In case of z, enol form is more stable due to the formation of H-bond, which is as shown below

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Hence, the relation between the keto contents is x>y>z

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