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Q.

The relationship between osmotic pressure at 273 K when 10 g glucose $(P_{1}), 10 g urea (P_{2})$ and 10 g sucrose $(P_{3})$ are dissolved in 250 mL of water is:

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a

$P_{2} > P_{3} > P_{1}$

b

$P_{2} > P_{1} > P_{3}$

c

$\begin{aligned} P_{3} > P_{1} > P_{2} \end{aligned}$

d

$\begin{aligned} P_{1} > P_{2} > P_{3} \end{aligned}$

answer is C.

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Detailed Solution

$n_{glucoвe} = \frac{10}{180}; n_{urea} = \frac{10}{60}; n_{aucrose} = \frac{10}{342}$

Cone. of urea > glucose > sucrose

$\Rightarrow π$ also follows same order.

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The relationship between osmotic pressure at 273 K when 10 g glucose P1,10g urea P2 and 10 g sucrose (P3) are dissolved in 250 mL of water is: