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Q.

The relationship between osmotic pressures (π1,π2   and  π3)  at a definite temperature when 1g glucose, 1 g urea and 1 g sucrose are dissolved in a litre of water is (assume i=1  for all)

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a

π3>π1>π2

b

π2>π1>π3

c

π2>π3>π1

d

π1>π2>π3

answer is C.

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Detailed Solution

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π=iCRT;  where, i=1  for each of the solution
πα1molecular  mass  of  solute  π2            >            π1            >            π3
                                   
urea         glucose            sucrose
(60)          (180)              (342)
 

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