Q.

The relative atomic mass of sodium is 23. Which of the following statements is not correct about sodium? 

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a

Atomic mass of sodium is 3.82×1026kg

b

Atomic mass of sodium is 23 u. 

c

The number of atoms  in 24 kg  of sodium is 6.022×1023

d

Molar mass of sodium is 23 g mol1

answer is D.

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Detailed Solution

Explanation:

  • 1. Atomic mass of sodium is 23 u: This is correct. The relative atomic mass of sodium is 23 atomic mass units (u), which is defined as 1/12 the mass of a carbon-12 atom.
  • 2. Atomic mass of sodium is 3.82×10−26 kg: This is also correct. The atomic mass in kilograms can be calculated as: 
    23 u × 1.6605×10−27 kg/u = 3.82×10−26 kg.
  • 3. Molar mass of sodium is 23 g/mol: This is correct. Molar mass represents the mass of 1 mole of sodium atoms, which equals 23 g/mol.
  • 4. The number of atoms in 24 kg of sodium is 6.022×1023: This is incorrect. The number of atoms can be calculated as follows:

    • Number of moles:
      Mass of sodium / Molar mass = 24 kg / 0.023 kg/mol = 1043.48 mol.
    • Number of atoms:
      Number of moles × Avogadro's number = 1043.48 mol × 6.022×1023 atoms/mol = 6.28×1026 atoms.

    The given value (6.022×1023) corresponds to only 1 mole of sodium, not 24 kg, making this statement incorrect.

Final Answer:

Option 4 is NOT correct.

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