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Q.

The relative reactivity of 10H, 20H and 30H in chlorination reaction has been found to be 1:3.8:5 respectively .
CH3CH2CH2CH3Cl2 light ,250CCH3CH2CH2CH2Cl+.CH3CH2CHClCH3                                                    1-Chlorobutane            2-Chlorobutane 
The percentage yield of (A) & (B) are expected to be

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a

80%,20%

b

28.3%,71.7%

c

38.3%61.7%

d

50 %,50%

answer is B.

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Detailed Solution

The relative rates of the two isomers is as follows
1 chlorobutane =numberof 10H X reactivity of 10H=6 X1.0=6 2 chlorobutane =numberof 20H X  reactivity of 20H =4 X 3.8=15.2 6+15.2=21.2
Percentage of 1 chlorobutane =  6/21.2 𝑥100 = 28.3
Percentage of 2 –chlorobutane = 15.2/21.2X100=71.6

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The relative reactivity of 10H, 20H and 30H in chlorination reaction has been found to be 1:3.8:5 respectively .CH3CH2CH2CH3Cl2 light ,250CCH3CH2CH2CH2Cl+.CH3CH2CHClCH3                                                    1-Chlorobutane            2-Chlorobutane The percentage yield of (A) & (B) are expected to be