Q.

The resistance of 0.5 N solution of an electro-lyte in a conductivity cell was found to be 45 ohms. If the electrodes in the cell are 2.2 cm apart and have an area of 3.8 cm2 then the equivalent conductance (in Scm2 eq–1) of a solution is 

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a

30.75

b

25.73

c

35.75

d

15.75

answer is A.

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Detailed Solution

Specific conductance (k)= 1R×(lA)                                                = 145×2.23.8                                                = 0.0128S cm-1.

Molar conductance (m) =k×1000molarity                                                = 0.0128 ×10000.5                                               = 25.73 S cm2 eq-1.

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