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Q.

The results given in the below table were obtained during kinetic studies of the following reaction: 

2A+BC+D

Experiment[A]/molL-1[B]/molL-1Initial rate/ molL-1min-1
I0.10.16.00×10-3
II0.10.22.40×10-2
III0.20.11.20×10-2
IVX0.27.20×10-2
V0.3Y2.88×10-1

X and Y in the given table are respectively:

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a

0.3, 0.3

b

0.4, 0.3

c

0.4, 0.4

d

0.3, 0.4

answer is A.

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Detailed Solution

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From rate law 

r=12d[A]dt=d[B]dt=K[A]x[B]y

6×103=K(0.1)x(0.1)y, 2.4×102=K(0.1)x(0.2)y

1.2×102=K(0.2)x(0.1)y, (3)÷(1)x=1, (2)÷(3)x=2

So, order with respect to A = 1

Order with respect to B = 2

(4)÷(3)→ (x0.2)×(0.20.1)2=7.2×1021.2×102, x=6×0.24, x = 0.3M

(5)÷(4)(y0.2)2=2.88×1017.2×102, y2=4×0.22, Y = 0.4M

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