Q.

The salt Al(OH)3 involved in the following two equilibria,

Al(OH)3(s)Al3+(aq)+3OH(aq),KspAl(OH)3(s)+OH(aq)Al(OH)4(aq),Kc

Which of the following relationship is CORRECT at which solubility is minimum?

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a

OH=KspKc1/3

b

OH=KcKsp1/4

c

OH=3KspKc1/4

d

OH=KspKc1/4

answer is D.

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Detailed Solution

Al(OH)3=Al3++Al(OH)4 S=KspOH3+KCOHdSdOH=3KspOH4+KC=0 OH=3KspKC4

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