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Q.

The schematic plot of In Keq versus inverse of temperature for a reaction is shown in the figure. The reaction must be

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a

one with negligible enthalpy change

b

highly spontaneous at ordinary temperature

c

exothermic

d

endothermic

answer is C.

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Detailed Solution

The variation of standard equilibrium constant with temperature is given by

dlnKeq°dT=ΔH°RT2 which on integeration gives lnKeq°=-ΔH°RT+ constant

The slope of the graph between lnKeq° and 1/T shown in the figure is positive. The slope as given by the above equation is -ΔH/R This means H is negative, hence, the reaction is exothermic.

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