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Q.

The shape/ structure of XeF5 and XeO3F2, respectively, are: 

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a

pentagonal planar and trigonal bipyramidal

b

trigonal bipyramidal and pentagonal planar

c

octahedral and square pyramidal

d

trigonal bipyramidal and trigonal bipyramidal 

answer is B.

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Detailed Solution

XeF5 has 2 lone pairs + 5 bond pairs = 7 hybrid orbitals

    

 sp3d3hybridization with 2 lone pairs

          

 Pentagonal planar.

 XeO3F2 has zero lone pairs + 5 bond pairs = 5 hybrid orbitals

          

 sp3d hybridization

          

 trigonal bypyramidal

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