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Q.

The slope of the line for the graph of log k versus 1T for the reaction, N2O52NO2+12O2 is -5000. Calculate the energy of activation of the reaction (kJ K1 mol1)

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a

9.57

b

957

c

0.957

d

95.7

answer is A.

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Detailed Solution

K=AeEa/RT

lnK=lnAEaRT

2.303logK=EaRT+2.303logAlogK=Ea2.303RT+logA

Slope =-Ea2.303R=-5000

Ea=5000×8.31×2.303×10-3

=95.7kJ k1 mol1

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