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Q.

The solubility of AgCN in a buffer solution of pH = 3 is x. The value of x is:

Assume:Nocyanocomplexisformed:KspAgCN=22x1016andKaHCN=6.2x1010

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a

0.625×106

b

1.9×105

c

2.2×1016

d

1.6×106

answer is B.

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Detailed Solution

AgCNAg+CNΘ                        H+CNΘH++CNΘKsp×1Ka=Ag+CNΘ×[HCN]H+CNΘ2.2×10-16×16.6×10-10=Δ.Δ10-3Δ2=10-830  Δ=1.9×10-5

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The solubility of AgCN in a buffer solution of pH = 3 is x. The value of x is:Assume:No cyano complex is formed : KspAgCN=22x10−16and KaHCN=6.2x10−10