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Q.

The solubility of anhydrous $A l C l_{3}$ and hydrated $A l C l_{3}$ in diethyl ether are $S_{1}$ and $S_{2},$ respectively. Then,

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a

$S_{1} = S_{2}$

b

$S_{1} > S_{2}$

c

$S_{1} < S_{2}$

d

$S_{1} < S_{2} b u t n o t S_{1} = S_{2}$

answer is B.

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Detailed Solution

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$A l C l_{3}$ is covalent, more soluble in organic solvents. Hydrated $A l C l_{3}$ is ionic less soluble in organic solvents.

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