Q.

The solubility of gases increases with increase of pressure. William Henry made a systematic investigation of the solubility of a gas in a liquid. According to Henry's law "the mass of a gas dissolved per unit volume of the solvent at constant temperature is directly proportional to the pressure of the gas in equilibrium with the solution". Dalton during the same period also concluded independently that the solubility of a gas in a liquid solution depends upon the partial pressure of the gas. If we use the mole fraction of gas in the solution as a measure of its solubility, then Henry's law can be modified as "the partial pressure of the gas in the vapour phase is directly proportional to the mole fraction of the gas in the solution:

(ii) The partial pressure of ethane over a saturated solution containing 6.56 x 10-2 g of ethane is 1 bar. If the solution contains 5.00 x 10-2 g of ethane then what will be the partial pressure (in bar) of the gas?

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a

0.762

b

5.0

c

3.81

d

1.312

answer is A.

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Detailed Solution

According to Henry's law, m = KH x P
6.56×102=KHX1KH=6.56×102
For another case,5×102=6.56×102×P

P=56.56=0.762

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