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The solubility of metal halides depends on their nature, lattice enthalpy and hydration enthalpy of
the individual ions. Amongst fluorides of alkali metals, the lowest solubility of LiF in water is due to

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ionic nature of lithium fluoride

high hydration enthalpy for lithium ion

low ionzation enthalpy of lithium atom

high lattice enthalpy

answer is B.

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Detailed Solution

Due to small size of Li⁺ and F^–, lattice enthalpy is much higher than hydration enthalpy.

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