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Q.

The solubility of Ag2CO3 in water at 25° C is 1 x 10-4 mole/litre. What is its solubility in 0.01 M Na2CO3 solution? Assume no hydrolysis of CO32 ion.

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a

6×106 mole/itre 

b

2×105 mole/litre 

c

105 mole/litre 

d

4×105 mole/itre 

answer is C.

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Detailed Solution

Ksp=4×1043=4×1012

Ag2CO32Ag+2s+CO320.01

4s2×0.01=4×1012s=105M

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The solubility of Ag2CO3 in water at 25° C is 1 x 10-4 mole/litre. What is its solubility in 0.01 M Na2CO3 solution? Assume no hydrolysis of CO32− ion.