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Q.

The solubility of AgCl(s) with solubility product 1.6×10-10 in 0.1M of NaCl solution would be

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a

1.6×10-9M

b

1.6×10-11M

c

1.26×10-5M

d

Zero

answer is B.

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Detailed Solution

 Let s be the solubility of AgCl in moles per litre

AgCl(aq)Ag(aq)++Cl(aq)-

    s                  s      s+0.1

                                                         0.1MNaCl solution also provides 0.1M Cl-ion 

Ksp=Ag+Cl-1.6×10-10=s(s+0.1)1.6×10-10=s(0.1) (s<<<<0.1)s=1.6×10-100.1=1.6×10-9M

 

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