Q.

The solubility of BaSO4 (molar mass= 233 g mol-1) in 100 mL solution is 9.32 x 10-4 g. Its solubility in  0.1 M Na2 SO4 solution will be

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a

1.6×108M

b

2.8×108M

c

1.9×108M

d

1.6×107M

answer is B.

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Detailed Solution

Solubility (in  mol/L) is s=9.32×104g233gmol11000mLL1100mL=4×105molL1

For the equilibrium BaSO4(s)Ba2+(aq)+SO42(aq),KsBaSO4=Ba2+SO42=s2=4×105molL1)2Solubility of BaSO4 in  0.1MNa2SO4  is Ba2+=KsBaSO4SO42=4.0×105molL120.1molL1=1.6×108M

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