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Q.

The solubility of KClO3 at several temperatures is shown in the accompanying diagram.

Question Image

A student mixes 10.0 g of  KClO3 with 45.0 g of H2O and stirs it for a long time at 60° C until the solution is completely clear then allows it to cool slowly 20° C where it remains clear. Which statement about the final clear mixture at 20° C is correct?

 

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a

It is an unsaturated solution and can be made saturated by increasing the temperature.

b

It is a supersaturated solution

c

It is an unsaturated solution and can be made saturated by decreasing the temperature.

d

It is a saturated solution

answer is D.

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Detailed Solution

A supersaturated solution can be created by heating a saturated solution, adding more solute, and then gradually cooling it. A supersaturated solution contains more dissolved solute than is necessary to create a saturated solution. By adding a few crystals of the solute to a supersaturated solution, more dissolved solute crystallizes.

Hence the correct option is D

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