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Q.

The solubility product of AgCI is 2.6×10-10 at 250C.  The solubility of NaCl in 0.2 M  AgNO3 solution is 

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a

1.61×10-5

b

1.3×10-9

c

1.82×10-4

d

1.82×10-9

answer is A.

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Detailed Solution

AgCI(s)Ag+(aq)+CI-(aq)

                         (s+0.2)       s

2.6×10-10=(s+0.2)s

2.6×10-10=s2+0.2s

2.6×10-10=0.2s

(s2 is negligible when compared with ‘s’)

s=2.6×10-100.2=1.3×10-9mol  L-1

 

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