Q.

The solubility product of BaSO4 in water is 1.5×109 . The molar solubility of BaSO4 in 0.1 M solution of Ba(NO3)2 is:

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a

1.5×10-8M

b

0.5×10-8M

c

2.0×10-8M

d

1.0×10-8M

answer is B.

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Detailed Solution

Let the solubility of  BaSO4= s mole

BaSO4Ba+2s+SO4-2s

BaSO4Ba+20.1+SO4-22(0.1)

[Ba+2]=s+0.1;[SO4-2]=s

Ksp=BaSO4

1.5×10-9=[s+0.1][S]=s2+0.1s

S is very small, neglect  s2

1.5×10-9=0.1s

S=1.5×10=8M

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