Q.

The solubility product of BaSO4 in water is 1.5x10-9. The molar solubility of BaSO4 in 0.1M solution of Ba(NO3)2 in

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a

0.5×10-8M

b

1.5×10-8M

c

1.0×10-8M

d

2.0×10-8M

answer is B.

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Detailed Solution

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Let the solubility of BaSO4=s mole
BaSO4Ba+2+SO42BaNO32Ba+2+2NO3Ba+2=s+0.1;SO42=s Ksp=BaSO41.5×109=[s+0.1][s]=s2+0.1s
s is very small; neglect s2
1.5×109=0.1sS=1.5×108M

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