Q.

The solubility product of Ni(OH)2  at 298 K is 4×1015 mol3dm9 . The pH value of, its aqueous and saturated solution is (round off to the nearest integer)

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answer is 9.

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Detailed Solution

Solution:  Ni(OH)2Nis2++2OH2s
              Ksp=[Ni2+][OH]2
 =S×(2S)2=4S3 2×1015(mol/L)3=4S3 2×1015mol3dm9=4S3
  Or     S=(24×1015)1/38×106molL
 [OH]=2S=2×8×106molL
 pOH=log10[OH] pOH=log10[16×106] pOH=6log16=4.9835 pH=14pOH=145=9

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