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Q.

The solubility product of PbI2 is 8.0×109. The solubility of lead iodide in 0.1 M solution of lead nitrate is x×106 the value of  x  is (Rounded off to the nearest integer.

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Detailed Solution

Ksp(PbI2)=8×109

Pb(NO3)2Pb2+(aq)+2NO3(aq)0.1M                   0.1M   0.1MPbI2(s)Pb(aq)2++2I(aq)                             S              2S[Pb2+]=S+0.1=0.1

i.e.,  [Pb2+][I]2=8×109

(0.1)(2s)2=8×109

s=1.41×106 M

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