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Q.

The solubility product of Pbl2 is 8.0×109. The solubility of lead iodide in 0.1 molar solution of lead nitrate is 

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a

2×10-4M

b

2×10-8M

c

4×10-8M

d

2×10-8M

answer is B.

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Detailed Solution

given [Ksp]Pbl2=8×108

To calculate solubility of Pbl2 in 0.1M solution of Pb(NO3)2.

(i) Pb(NO3)2Pb2+(aq)+2NO3(aq)

(ii)            0.1¯M       0.1¯M                0.2¯MPbl2(s)Pb2+(aq)+2l(aq)                         s                       2s

[Pb2+]=S+0.10.1                  S<<0.1

Now, Ksp=8×109

[Pb2][I]2=8×109

0.1×(2S)2=8×109

4S2=8×108S=2×108M

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