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Q.

The solubility product of Cr(OH)3 at 298 K is 6.0×10-31. The concentration of hydroxide ions in a saturated solution of Cr(OH)3 will be

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a

18×10-311/4

b

2.22×10-311/4

c

4.86×10-291/4

answer is D.

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Detailed Solution

 The solubility product of Cr(OH)3 at 298 K is 6.0×10-31.

Cr(OH)3Cr+3+3OH-

s                       o         o

  •                s         3s

Ksp=(S)(3S)3

6×10-31=27 S4

 S4=6×10-3127

 S=6×10-31271/4

OH-=3 S=3×6×10-31271/4

=(81)1/4×6×10-31271/4

OH-=81×627×10-311/4=18×10-311/4

Hence the correct option is (D) 18×10-311/4

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