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The solution which show large positive deviation from Raoult's law form

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minimum boiling azeotrope at a specific composition

maximum freezing azeotrope at a specific composition

minimum freezing azeotrope at a specific composition

maximum boiling azeotrope at a specific composition

answer is A.

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Detailed Solution

Only non-ideal solutions form azeotropic mixtures (constant boiling mixtures). Among the given, only CCl₄ and CHCI₃ form non-ideal solution, thus they form azeotropic mixture.

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