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Q.

The species that has a spin only magnetic moment of 5.9 BM, is ( Td=tetrahedral)

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a

Ni(CO)4(Td)

b

[NiCl4]2(Td)

c

[Ni(CN)4]2 -(square planar)

d

[MnBr4]2(Td)

answer is D.

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Detailed Solution

=5.9BM

 Number of unpaired electrons = 5
[MnBr4]2   Mn2+=[Ar]3d54s0
Question Image
BrΘ is a weak field ligand.
n=5  μ=5(5+2)BM=5.9BM
 

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