The specific conductivity of dichloroacetic acid at dilution of 8 litres is 0.0238 C.G.S. unit, $λ_{o}$ for this acid is 385 C.G.S. unit, calculate the degree of ionisation at this dilution.

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45%

36.02%

50%

49.45%

answer is C.

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Detailed Solution

$\begin{array}{l} \land_{M} = K \times V (ml) = 0 .0238 \times 8 \times 1000 = 190 .4 \\ α = Λ_{M} / Λ_{M}^{0} = 190 .4 \times 100 / 385 = 49 .45 % \end{array}$

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