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Q.

The 'spin-only' magnetic moment [in units of Bohr magneton μB] of Ni+2 in aqueous solution would be: (Atomic number of Ni = 28)

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a

2.84

b

4.90

c

0

d

1.73

answer is A.

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Detailed Solution

Since water is a weak ligand in aqueous solutions, high spin complexes develop.
Electrical arrangement of Nii=[Ar]4s23d8

Electrical arrangement of Ni2+=[Ar]4s03d8

Ni+2,d8 two unpaired electrons in the arrangement, the magnetic moment is:

μ=n(n+2)=2×4=2.84BM

As a result, choice A is accurate.

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