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Q.

The spine! structure AB2O4 consists of an fee array of O2 ions in which the :

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a

A cation occupies one-eighth of the octahedral hole and the B cations the tetrahedral holes

b

A cation occupies one-fourth of the octahedral holes and B cations the tetrahedral holes

c

A cation occupies one-fourth of the tetrahedral holes and the B cations the octahedral holes

d

A cation occupies one-eighth of the tetrahedral holes and B cation occupies one-half of octahedral hole

answer is A.

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Detailed Solution

A cation occupies one-eighth of the tetrahedral holes and B cation occupies one-half of the octahedral hole. In case of spinel O2ions occupy the FCC array, A2+ occupies one-eighth of tetrahedral voids and the B3+cations occupy the half of the octahedral voids. The correct option is A.

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