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Q.

The stability of given free radicals in decreasing order is

1)CH3-CH2

2)CH3-CH-CH3

3)Question Image

4)CH3

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a

1>2>3>4

b

3>4>1>2

c

3>2>1>4

d

3>2>4>1

answer is D.

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Detailed Solution

For a given free radicals, if the alkyl groups attached are increases then positive inductive effect (+I.E) is increased and then stability also increased. Among given all free radicals, tertiary butyl radical is most stable. The decreasing order of stability of free radicals is 3>2>1>4

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The stability of given free radicals in decreasing order is1)CH3-C∙H22)CH3-C∙H-CH33)4)C∙H3