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The stability of interhalogen compounds.

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a

${BrF}_{3} > {ClF}_{3} > {IF}_{3}$

b

${BrF}_{3} > {IF}_{3} > {CIF}_{3}$

c

${ClF}_{3} > {BrF}_{3} > {IF}_{3}$

d

${ClF}_{3} > {IF}_{3} > {BrF}_{3}$

answer is A.

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Detailed Solution

Interhalogen bond strength increases with increase in the difference of electro negativity. I–F bond is stronger and thus IF₃ must be more stable but it is very unstable and dispropotionates because fluorine oxidizes the iodine to higher oxidation state forming IF₅ of IF₇.

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