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Q.

The standard electrode potentials, in aqueous solutions, of Li, Na and K are –3.05V, 
–2.71V and –2.93V respectively. It is found that Li reacts gently with water whereas potassium reacts violently with water. Which of the following statement(s) is/are correct regarding the above two experimental facts?

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a

Ionization potential of K is more than Lithium.

b

Enthalpy of hydration of Potassium is less negative than Lithium.

c

More negative is Standard free energy change of the reaction, faster is the reaction.

d

Due to lower melting point of K, heat of reaction released melts to increase surface area than Li.

answer is B, D.

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Detailed Solution

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Increase in surface area increases rate of reaction.

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