Q.

The standard e.m.f. of a galvanic cell involving cell reaction with n = 2 is found to be 0.295 V at 250C. The equilibrium constant of the reaction
would be  F=96500Cmol1;R=8.314JK1mol1

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a

1.0 × 102

b

4.0 × 1012

c

1.0 × 1010

d

2.0 × 1011

answer is A.

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Detailed Solution

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log Keq=nFEcello2.303RT              = 2×96500×0.2952.303×8.314×298 log Keq =9.97        Keq  =109.971× 1010 

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