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The standard EMF of the cell reaction, $2 A g^{+} + C u \to 2 A g + C u^{+ 2}$ is 0.46 V. If $E_{C u^{+ 2} / C u}^{0}$ is + 0.34V, then $E_{A g^{+} / A g}^{0}$ value is

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0.80 V

0.40 V

0.12 V

1.60 V

answer is B.

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Detailed Solution

$E . M . F = E_{c a t h o d e}^{0} - E_{a n o d e}^{0}$

$0.46 = x - 0.34$

$x = 0.80 V$

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