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Q.

The standard enthalpies of formation of CO2(g), H2O(l) and glucose (s) at 25°C are –400 kJ/mole, –300 kJ/mole, –1300 kJ/mole respectively. The standard enthalpy of combustion per gram of glucose at 25°C is:

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a

–2900 kJ

b

+2900 kJ

c

–16.11 kJ

d

+16.11 kJ

answer is C.

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Detailed Solution

C6H12O6(s) + 6O2(g) → 6CO2 (g) + 6H2O(l)
Δr0H=6Δf0H(CO2)+6Δf0HH2OΔf0H(C6H12O6) 
= 6 x (–400) + 6(–300) – (–1300)
= –2400 – 1800 + 1300 = –2900 kJ/mol
Hence, standard enthalpy of combustion per gram of glucose =2900180kJ/g=16.11kJ/g

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