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Q.

The standard enthalpies of formation of  CO2(g),H2O(l) and  glucose(s) at 25C are 400kJ/mol,300kJ/mol and 1300 kJ/mol, respectively. The standard enthalpy of combustion per gram of glucose at 25° is

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a

+16.11kJ 

b

-—2900kJ 

c

+2900kJ 

d

-16.11kJ 

answer is C.

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Detailed Solution

The standard enthalpy of the combustion of glucose can be calculated by the eqn. 
C6H12O6(s)+6O2(g)6CO2(g)+6H2O(l) ΔHCo=6×ΔHfCO2+6×ΔHfH2OΔHfC6H12O6 ΔHCo=6(400)+6(300)(1300) ΔHCo=2900kJ/mol
For one gram of glucose, enthalpy of combustion 
ΔH=2900180=16.11kJ/gm

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