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Q.

The standard enthalpies of formation of CO2(g),H2O(),glucose(s) at 250C are 400kJ/ mole, 300kJ/mole, and 1300kJ/molerespectively. The standard enthalpy of combustion per gram of glucose at 25° C is 

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a

-16.11kJ

b

+2900 kJ

c

-2900 kJ

d

+16.11kJ

answer is C.

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Detailed Solution

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C6H12O6+6O26CO2+6H2O(s)                (g)         (g)        ()ΔHcombustion =6×ΔHfCO2+6×ΔHfH2OΔHfC6H12O6ΔH0=6(400)+6(300)(1300)=2900kJ/mol
For one gram of glucose enthalpy of
Combustion ΔH0=2900180=16.11kJ/gr

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