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Q.

The standard enthalpy and entropy changes for a reversible reaction are given below:  
at  300K,ΔH0=40kJ mol-1;ΔS0=4×102kJ mol-1
at 1200K,ΔH0=33 kJ mol-1;ΔS0=3×102kJ mol-1. (consider R=8 joules per kelvin (K) per mole.) Identify correct statements.

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a

The reaction is reactant favorable at 1200 K

b

When temperature is raised from  300K to 1200K, the reaction proceeds in the forward direction

c

The reaction is product favorable at 1200 K

d

The reaction is product favorable at 300 K.

answer is A, C.

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Detailed Solution

At  300K,  ΔG0=ΔH0TΔS0=28.44 kJ/mole proceeds in forward direction
At  1200K,  ΔG0=+2.59 kJ/mole proceeds in reverse direction
 

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