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Q.

The standard enthalpy of combustion at 25 °C of H2(g) cyclohexene(g) and cyclohexane(g) are - 241, - 3800 and −3920 kJ mol−1 respectively. The standard enthalpy of hydrogenation of cyclohexene will be

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a

−121 kJ mol−1

b

121 kJ mol−1

c

−242 kJ mol−1

d

−1211 kJ mol−1

answer is C.

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Detailed Solution

C6H10(g)+H2(g)→C6H12(g)

(I) C6H12(g)+9O2(g)→6CO2(g)+6H2O(l)

 (ii) C6H10(g)+172O2(g)→6CO2(g)+5H2O (1) 

 (iii) H2(g)+12O2(g)→H2O(l)

ΔH=ΔH(ii) +ΔH(iii) −ΔH(i)  =[−3800−241−(−3920)]kJmol−1 =−121kJmol−1

Thus the option C is correct.

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