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Q.

The standard enthalpy of formation (Hf0 ) at 298 K for methane,CH4(g), is 74.8 KJ/mol. The additional information required to determine the average energy for C-H bond formation would be

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a

The dissociation energy of hydrogen molecule, H2

b

Latent heat of vaporisation of methane.

c

The first four ionisation energies of carbon and electron gain enthalpy of hydrogen

d

The dissociation energy of H2 and enthalpy of sublimation of carbon

answer is B.

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Detailed Solution

Heat of formation of CH4 is represented as 

C(g) + 2H2(g)CH4(g)

standard condition of carbon is graphite and is converted into gaseous carbon, sublimation energy is required

H2 molecule is dissociated into hydrogen atoms, bond dissociation energy of hydrogen molecule is required

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The standard enthalpy of formation (∆Hf0 ) at 298 K for methane,CH4(g), is 74.8 KJ/mol. The additional information required to determine the average energy for C-H bond formation would be