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Q.

The standard enthalpy of formation of gaseous H2O at 298 K is -242 kJ mol-1. Calculate ΔH at 373 K given the following values of the molar heat capacities at constant pressure. 

Molar heat capacity of H2O(g)=33.5 JK-1 mol-1 

Molar heat capacity of H2(g)=28.8 JK-1 1mol-1

Molar heat capacity of O2(g)=29.4 JK-1mol-1 

{Assume that the heat capacities are independent of temperature.}

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a

 508 kJ mol-1

b

-242.75 kJ mol-1

c

-242 kJ mol-1

d

None of these

answer is C.

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Detailed Solution

For given reaction,

H2(g)+12O2(g)H2O(g)

The value of the

ΔCP=33.528.812×29.4=10

ΔH373=24210×751000=242.75

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