Q.

The standard enthalpy of formation of  NH3 is 46.0kJmol1If the enthalpy of formation of H2, from its atoms is 436kJmol1 and that of N2 is 712kJmol1the average bond enthalpy of N — H bond in NH3, is

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a

+1056kJmol1

b

1102kJmol1

c

964kJmol1

d

+352kJmol1

answer is B.

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Detailed Solution

N2+3H22NH3 ΔH=2×46.0kJmol1
Let x be the bond enthalpy of N — H bond then 
[Note : Enthalpy of formation or bond formation enthalpy is given which is negative but the given reaction involves bond breaking hence values should be taken as positive.] ΔH=Σ Bond energies of reactants Σ Bond energies of products 
2×46=712+3×(436)6x 92=20206x 6x=2020+92 6x=2112 x=+352kJ/mol

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