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Q.

The standard enthalpy of formation ΔfH at 298 K for methane, CH4(g), is 78.4kJmol1. The additional information required to determine the average for CH bond formation would be

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a

latent heat of vapourization of methane

b

the dissociation energy of hydrogen molecule, H2

c

the dissociation energy of H2 and enthalpy of sublimation of carbon

d

the first four ionization energies of carbon and electron gain enthalpy of hydrogen

answer is B.

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Detailed Solution

The given information is C (graphite) +2H2(g)CH4(g);                     ΔfH=74.84kJmol1

To determine the average energy of CH we refer to the reaction CH4(g)C(g)+4H(g)

Hence, in addition to  ΔfHCH4, we must have data on the dissociation energy of H2 and enthalpy of sublimation of carbon.

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